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Synthesis of amine incorporated hierarchical metal organic framework (MOF) MIL-101(Cr)/SBA-15, meso/ micro-porous composites, with tailored properties for CO 2 capture is reported. The synthesized composites were characterized in terms of their crystallinity, morphology, functional groups, and textural properties. Isothermal adsorption of CO 2 from concentrated sites as well as ambient conditions were evaluated by gravimetric and volumetric measurements. The optimized composite i.e., MIL-101(Cr)/SBA-15/PEI-25 showed improved pseudo- equilibrium adsorption capacity of 3.2 mmol/g at 303 K and 1 bar, compared to nascent SBA-15 (0.8 mmol/g) and the MOF, i.e., MIL-101(Cr) (1.3 mmol/g). Such adsorption performance can be attributed to the basic sites of the impregnated polyethyleneimine (PEI), unsaturated Cr(III) metal sites, and the hierarchical pore structure of the composite which imparts chemical as well physical adsorption forces towards CO 2 lower amine loading of 25 wt% in the composite resulted in facile CO 2 uptake. Interestingly, desorption at much lower temperature of 

The effects of adding Mn and Na promoter metals to graphene oxide (GO)-supported iron-based catalysts for Ficher-Tropsch Synthesis (FTS) reactions to olefins at 20 bars were investigated in a 3D-printed stainless steel (SS) Microreactor. While promoter metals encourage reduction of iron oxide to iron to form iron carbide, the active metal catalysts in GO allow hydrogenation of CO. These catalysts were synthesized by layer deposition method and characterized by different techniques. The TEM images show the integration of graphene oxide into the catalysts. The XRD and XPS studies confirmed the crystal structure and oxidation states of the metals. The catalytic activity and product selectivity were studied in the temperature range of 200–350°Cwith a 2:1 M ratio of H2: CO. Higher CO conversion with greater selectivity for olefins was observed in the presence of the promoters. FeMnNa@GO showed better stability than both Fe@GO and FeMn@GO catalysts in time-on-stream studies. 

Ni/SBA-15 meso-structured catalysts modified with chromium and CeO2 (Ni–Cr-CeO2/SBA-15) were utilized to produce hydrogen from glycerol steam reforming (GSR). The catalysts were synthesized by a one-pot hydrothermal process and extensively characterized by analytical techniques such as N2 adsorption–desorption (BET), H2-temperature programmed reduction (H2-TPR), powder X-ray diffraction (PXRD), inductively coupled plasma-optical emission spectrometry (ICP-OES), and transmission electron microscopy (TEM). The low-angle XRD reflections affirmed that the catalysts were crystalline and possessed a 2D-ordered porosity. The BET results depicted that all the catalysts exhibited a good surface area ranging from 633 to 792m2/g, and the pore sizes were consistently in the mesoporous range (between 3 and 5 nm). TEM analysis of both calcined and spent catalysts revealed that the metal active sites were embedded in the hybrid CeO2-SiO2 support. Overall, the Ni-based catalysts exhibited higher glycerol conversion -12Ni-SBA-15–99.9%, 12Ni3CeO2-SBA-15–89.4%, and 8Ni4Cr3CeO2-SBA-15–99.7%. Monometallic 12Ni/SBA-15 performed exceptionally well, while 12Cr/SBA-15 performed poorly with the highest 71.48% CO selectivity. For short-term GSR reactions, CeO2 addition to 12Ni/SBA-15 did not have any effect, whereas Cr addition resulted in a 32% decrease in H2 selectivity. The long-term stability studies of 12Ni-SBA-15 showed H2 selectivity of ~ 64% and ~ 98% glycerol conversion. However, its activity was short-lived. After 20–30 h, the H2 selectivity and conversion dropped precipitously to 40%. The doping of mesoporous Ni/SBA-15 with Cr and CeO2 remarkably enhanced the long-term stability of the catalyst for 12Ni3CeO2-SBA-15, and 8Ni4Cr3CeO2-SBA-15 catalyst which showed ~ 58% H2 selectivity and ~ 100% conversion for the entire 60 h. Interestingly, Cr and CeO2 seem to improve the shelf-life of Ni-SBA-15 via different mechanistic pathways. CeO2 mitigated Ni poisoning through coke oxidation whereas Cr bolstered the catalyst stability via maintaining a well-defined pore size, structural rigidity, and integrity of the heterogeneous framework, thereby restricting structural collapse, and hence retard sintering of the Ni active sites during the long-term 60 h of continuous reaction. Hydrogen generation from renewable biomass like glycerol could potentially serve as a sustainable energy source and could substantially help reduce the carbon footprint of the environment 

Regular expressions are used for diverse purposes, including input validation and firewalls. Unfortunately, they can also lead to a security vulnerability called ReDoS (Regular Expression Denial of Service), caused by a super-linear worst-case execution time during regex matching. Due to the severity and prevalence of ReDoS, past work proposed automatic tools to detect and fix regexes. Although these tools were evaluated in automatic experiments, their usability has not yet been studied; usability has not been a focus of prior work. Our insight is that the usability of existing tools to detect and fix regexes will improve if we complement them with anti-patterns and fix strategies of vulnerable regexes. We developed novel anti-patterns for vulnerable regexes, and a collection of fix strategies to fix them. We derived our anti-patterns and fix strategies from a novel theory of regex infinite ambiguity — a necessary condition for regexes vulnerable to ReDoS. We proved the soundness and completeness of our theory. We evaluated the effectiveness of our anti-patterns, both in an automatic experiment and when applied manually. Then, we evaluated how much our anti-patterns and fix strategies improve developers’ understanding of the outcome of detection and fixing tools. Our evaluation found that our anti-patterns were effective over a large dataset of regexes (N=209,188): 100% precision and 99% recall, improving the state of the art 50% precision and 87% recall. Our anti-patterns were also more effective than the state of the art when applied manually (N=20): 100% developers applied them effectively vs. 50% for the state of the art. Finally, our anti-patterns and fix strategies increased developers’ understanding using automatic tools (N=9): from median “Very weakly” to median “Strongly” when detecting vulnerabilities, and from median “Very weakly” to median “Very strongly” when fixing them. 

This paper presents a holographic fabrication of a new type of photonic crystal, called graded photonic super-crystals with graded basis, dual period and dual symmetry. Pixel-by-pixel phase coding of laser beams in a spatial light modulator can produce the highest resolution in produced photonic super-lattice. Two-level designs in phase pattern are used to generate graded photonic super-crystals where graded square lattice clusters are orientated in four, five or six-fold symmetry. Further phase engineering in a super-cell of 12x8 pixels can produce small-period square lattice orientated in a large period rectangular pattern. 

This paper presents a search for massive, charged, long-lived particles with the ATLAS detector at the Large Hadron Collider using an integrated luminosity of $$140~fb^{−1}$$ of proton-proton collisions at $$\sqrt{s}=13$$~TeV. These particles are expected to move significantly slower than the speed of light. In this paper, two signal regions provide complementary sensitivity. In one region, events are selected with at least one charged-particle track with high transverse momentum, large specific ionisation measured in the pixel detector, and time of flight to the hadronic calorimeter inconsistent with the speed of light. In the other region, events are selected with at least two tracks of opposite charge which both have a high transverse momentum and an anomalously large specific ionisation. The search is sensitive to particles with lifetimes greater than about 3 ns with masses ranging from 200 GeV to 3 TeV. The results are interpreted to set constraints on the supersymmetric pair production of long-lived R-hadrons, charginos and staus, with mass limits extending beyond those from previous searches in broad ranges of lifetime